\begin{tabular}{ccccccc}
\hline
$n$&$1$&$2$&$3$&$4$&5&6\\
\hline
$Na^{\scriptscriptstyle{+}}$&$3$&$4$&$5$&$6$&6&7\\
$K^{\scriptscriptstyle{+}}$&$2$&$4$&$5$&$7$&7.2&8\\
$Ca^{\scriptscriptstyle{2+}}$&$9$&$10$&$10.5$&$11.2$&11.5&11.9\\
\hline
\end{tabular}
\documentclass{article}
\usepackage{tabularx}
\usepackage{booktabs}
\usepackage[version=4]{mhchem}
\usepackage{array}
\begin{document}
\begin{tabularx}{1\linewidth}{*{7}{>{\centering\arraybackslash}X}}
\toprule
\(n\) & 1 & 2 & 3 & 4 & 5 & 6\\
\midrule
\ce{Na^+} & 3 & 4 & 5 & 6 & 6 & 7\\
\ce{K^+} & 2 & 4 & 5 & 7 & 7.2 & 8\\
\ce{Ca^2+} & 9 & 10 & 10.5 & 11.2 & 11.5 & 11.9\\
\bottomrule
\end{tabularx}
\end{document}
\documentclass{standalone}
\usepackage{nicematrix}
\begin{document}
\begin{NiceTabular}[columns-width = 1cm]{ccccccc}
\hline
$n$&$1$&$2$&$3$&$4$&5&6\\
\hline
$Na^{\scriptscriptstyle{+}}$&$3$&$4$&$5$&$6$&6&7\\
$K^{\scriptscriptstyle{+}}$&$2$&$4$&$5$&$7$&7.2&8\\
$Ca^{\scriptscriptstyle{2+}}$&$9$&$10$&$10.5$&$11.2$&11.5&11.9\\
\hline
\end{NiceTabular}
\end{document}
用 tabularx 即可,参考代码,如果用 Y 参数就是居中对齐,如果是 X 参数就是左对齐,自己选择吧:
\documentclass{ctexart}
\usepackage{amsmath}
\usepackage{array,tabularx}
\newcolumntype{Y}{>{\centering\arraybackslash}X}
\begin{document}
\begin{tabularx}{10cm}{YYYYYYY}
\hline
$n$&$ 1$&$ 2$&$ 3$&$4$&5&6\\
\hline
$Na^{\scriptscriptstyle{+} }$&$3$&$4$&$ 5$&$6$&6&7\\
$K^{\scriptscriptstyle{+}}$&$2$&$4$&$5$&$7$&7. 2&8\\
$Ca^{\scriptscriptstyle{2+}}$&$9$&$10$&$10.5$&$11.2$&11.5&11.9\\
\hline
\end{tabularx}
\end{document}
效果: